Popsugar Celebrity And Entertainment Relationship Timeline Brad Pitt and Angelina Jolie's Relationship Timeline Brad Pitt and Angelina Jolie's Relationship Timeline 20 September, 2016 by Lauren Turner View On One Page Photo 1 of 21 ADVERTISEMENT () Start Slideshow Share This Link Copy ← Use Arrow Keys → 1 March 2005 Brad and Angelina kept their distance during a promotional appearance for Mr. and Mrs. Smith. A week later, Jennifer Aniston officially filed for divorce from Brad following the January announcement of their separation. Previous Next Start Slideshow Relationship TimelineAngelina JolieBrad PittCelebrity Couples